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Synthesis of In2O3-In2S3 core-shell nanorods with inverted type-I structure for photocatalytic H2 generation

Identifieur interne : 000398 ( Main/Repository ); précédent : 000397; suivant : 000399

Synthesis of In2O3-In2S3 core-shell nanorods with inverted type-I structure for photocatalytic H2 generation

Auteurs : RBID : Pascal:13-0276125

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English descriptors

Abstract

In2O3-In2S3 core-shell nanostructures were prepared via a simple hydrothermal process at low temperatures. Ultraviolet photoelectron spectroscopy (UPS) shows that the In2O3-In2S3 nanorod is an inverted type 1 nanostructure. The energy potential in this structure would drive both the photo-generated holes and electrons towards the shell to facilitate photocatalytic H2 generation. Such inverted type-I nanostructure is firstly used for hydrogen generation. Comparing with reported indium-based photocatalysts upon UV-Vis illumination, the core-shell In2O3-In2S3 nanostructure obtained here exhibits a good H2 evolution rate of 61.4 μmol h-1 g-1.

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Pascal:13-0276125

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<title xml:lang="en" level="a">Synthesis of In
<sub>2</sub>
O
<sub>3</sub>
-In
<sub>2</sub>
S
<sub>3</sub>
core-shell nanorods with inverted type-I structure for photocatalytic H
<sub>2</sub>
generation</title>
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<div type="abstract" xml:lang="en">In
<sub>2</sub>
O
<sub>3</sub>
-In
<sub>2</sub>
S
<sub>3</sub>
core-shell nanostructures were prepared via a simple hydrothermal process at low temperatures. Ultraviolet photoelectron spectroscopy (UPS) shows that the In
<sub>2</sub>
O
<sub>3</sub>
-In
<sub>2</sub>
S
<sub>3</sub>
nanorod is an inverted type 1 nanostructure. The energy potential in this structure would drive both the photo-generated holes and electrons towards the shell to facilitate photocatalytic H
<sub>2</sub>
generation. Such inverted type-I nanostructure is firstly used for hydrogen generation. Comparing with reported indium-based photocatalysts upon UV-Vis illumination, the core-shell In
<sub>2</sub>
O
<sub>3</sub>
-In
<sub>2</sub>
S
<sub>3</sub>
nanostructure obtained here exhibits a good H
<sub>2</sub>
evolution rate of 61.4 μmol h
<sup>-1</sup>
g
<sup>-1</sup>
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<sub>3</sub>
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<sub>2</sub>
O
<sub>3</sub>
-In
<sub>2</sub>
S
<sub>3</sub>
nanorod is an inverted type 1 nanostructure. The energy potential in this structure would drive both the photo-generated holes and electrons towards the shell to facilitate photocatalytic H
<sub>2</sub>
generation. Such inverted type-I nanostructure is firstly used for hydrogen generation. Comparing with reported indium-based photocatalysts upon UV-Vis illumination, the core-shell In
<sub>2</sub>
O
<sub>3</sub>
-In
<sub>2</sub>
S
<sub>3</sub>
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<sub>2</sub>
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